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Reaction Intermediates and Bond Cleavage Class 11 Chemistry MCQs with Answers
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CBSE Class 11 Chemistry Quiz – Reaction Mechanisms and Bond Cleavage
Introduction Paragraph
Strengthen your understanding of Reaction Intermediates and Bond Cleavage with this set of CBSE Class 11 Chemistry MCQs, designed strictly as per the NCERT syllabus. This topic from Chapter 12: Organic Chemistry – Some Basic Principles and Techniques focuses on how chemical bonds break and how reactive species such as carbocations, carbanions, free radicals, and carbenes are formed during organic reactions.
Each question in this online practice test includes instant scoring, detailed feedback, and explanations to help students grasp the key concepts behind homolytic and heterolytic bond fission, as well as the stability of different intermediates.
These MCQs are ideal for CBSE Class 11 board exam preparation and are equally useful for NEET, JEE, and other entrance exams. Practice these questions to master the logic of reaction mechanisms and bond behavior in organic chemistry — a foundation for all advanced organic reaction studies.
Sample MCQs (with Answers and Explanations):
Q1. Homolytic bond cleavage leads to the formation of:
A) Ions B) Free radicals C) Carbanions D) Carbocations
✅ Answer: B) Free radicals
💡 Explanation: In homolytic fission, each atom takes one electron from the shared pair, producing radicals with unpaired electrons.
Q2. The heterolytic cleavage of H–Cl produces:
A) H• and Cl• B) H⁺ and Cl⁻ C) H⁻ and Cl⁺ D) H₂ and Cl₂
✅ Answer: B) H⁺ and Cl⁻
💡 Explanation: In heterolytic cleavage, the more electronegative atom (Cl) takes both bonding electrons, forming Cl⁻ and H⁺.
Q3. The intermediate formed in an SN1 reaction is:
A) Carbanion B) Carbocation C) Radical D) Carbene
✅ Answer: B) Carbocation
💡 Explanation: SN1 reactions proceed through carbocation intermediates after the leaving group departs.
Q4. Which of the following intermediates is neutral but highly reactive?
A) Carbocation B) Carbanion C) Radical D) Carbene
✅ Answer: D) Carbene
💡 Explanation: A carbene is a neutral divalent carbon species with two nonbonded electrons, making it highly reactive.
Q5. The stability order of carbocations is:
A) 1° > 2° > 3° B) 3° > 2° > 1° C) 2° > 1° > 3° D) 1° = 3° > 2°
✅ Answer: B) 3° > 2° > 1°
💡 Explanation: Tertiary carbocations are stabilized by hyperconjugation and inductive effects of surrounding alkyl groups.
